Fr. Li Ping-he李平和
Position: Founding principal, clergyman
Years: From the school's founding (Exact year not specified, but likely from 1964)
Vice-Bishop Chen Hua-liu陳驊騮
Position: Vice-bishop, clergyman
Years: Served for about 3 to 4 years after Fr. Li Ping-he
Fr. He Ren-long賀人龍
Position: Clergyman
Years: Served for about 3 to 4 years after Vice-Bishop Chen Hua-liu
Fr. Fan Wen-zhong范文忠
Position: Clergyman
Years: Served for about 3 to 4 years after Fr. He Ren-long
Principal Chen Ming-qing陳明清
Position: Layperson, not a clergyman
Years: Took office in 1975 (ROC Year 64), served for over 10 years
Achievements: Known for outstanding school management, doubling the number of students. Awarded the Papal Order of Saint Gregory the Great and the title of Commander.
Principal Wang Jia-yi汪甲一
Position: Principal
Years: Took office in 1989 (ROC Year 78)
Achievements: Focused on stable development; awarded the Papal Equestrian Order of St. Sylvester.
Principal Wang Xin-hua王新化
Position: Principal
Years: Took office in 2001 (ROC Year 90)
Achievements: Institutionalized and made school management more transparent, following the school motto of "Sincerity, Simplicity, Diligence, and Frugality."
Principal Chen Fang-ji陳方濟
Position: Principal
Years: Took office in 2013 (ROC Year 102)
Achievements: Actively promoted school development, upgrading school facilities, fostering cooperation with universities and enterprises, and earned the Ministry of Education's top school rating for consecutive years.